77067-12-0Relevant academic research and scientific papers
SYNTHESIS OF Δ3-DIHYDROTHIAPYRAN-1,1-DIOXIDES AND THEIR RAMBERG-BAECKLUND CONVERSION TO CYCLOPENTADIENES.
Burger, Jack J.,Chen, Tjoe B.R.A.,Waard, Eddy R. de,Huisman, Henk O.
, p. 1739 - 1742 (2007/10/02)
Treatment of Z-sulfone 1 with n-BuLi gives complete conversion to the cyclized anion 3.The anion 3 is protonated to 4.Reaction of 3 with hexachloroethane leads to a mixture of 4, 5 and 6.Ramberg-Baecklund rearrangement of 5 with one equivalent of n-BuLi a
