77067-72-2Relevant academic research and scientific papers
DIELS-ALDER REACTIONS OF (1E),(3E)-2-METHYL-1-TRIMETHYLSILYLOXY-1,3-PENTADIENE AND THE SYNTHESIS OF MULTISTRIATINS FROM THE ADDUCTS
Mori, Yuji,Inaba, Mitsutoshi,Suzuki, Makuto
, p. 3488 - 3491 (2007/10/02)
The Diels-Alder reactions of (1E),(3E)-2-methyl-1-trimethylsilyloxy-1,3-pentadiene with methyl acrylate and methyl (2E)-pentenoate were investigated.One of the adducts was used to synthesize some multistriatins.Keywords - (1E),(3E)-2-methyl-1-trimethylsil
Stereospecific 1,4-Additions of Methyl Cyanocuprate to Enol Phosphates of α,β-Epoxycyclohexanones: Application to the Total Synthesis of (+/-)-α-Multistriatin
Marino, Joseph P.,Abe, Hiroyuki
, p. 5379 - 5383 (2007/10/02)
A highly stereospecific synthesis of (+/-)-α-multistriatin, one of the three components of the aggregation pheromone of the European elm bark beetle, is described.The synthesis involves a new route to substituted cyclohex-2-en-1-ols via trans 1,4-addition
