77078-79-6Relevant academic research and scientific papers
Stereoselective Epoxidation of 3-trans-Benzylideneisoborneol
Sanghvi, Y. S.,Rao, A. S.
, p. 317 - 320 (2007/10/02)
2-Benzylidenecyclopentanol (2) can be epoxidized stereoselectively to furnish 2-trans-benzylidene-1β-hydroxycylopentane β-oxide (4) with either t-butyl hydroperoxide in the presence of vanadium catalyst or m-chloroperoxybenzoic acid.Epoxidation of 3-trans
Stereoselektive Synthese von Alkoholen, VI. Asymmetrische Synthesen von 4-Penten-2-ol ueber Allylboronsaeureester chiraler Glycole
Herold, Thomas,Schrott, Ursula,Hoffmann, Reinhard W.
, p. 359 - 374 (2007/10/02)
Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1).The substituents affect the extent of asymmetric induction in an additive manner.Pentenol of 86percent enantiomeric purity was obtained using 2d as chiral matrix.
