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Benzoic acid, 4-methoxy-, 3-bromobicyclo[2.2.1]hept-2-yl ester, (2-exo,3-endo)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

77085-45-1

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77085-45-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 77085-45-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,0,8 and 5 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 77085-45:
(7*7)+(6*7)+(5*0)+(4*8)+(3*5)+(2*4)+(1*5)=151
151 % 10 = 1
So 77085-45-1 is a valid CAS Registry Number.

77085-45-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name bromo-2 endo p-methoxybenzoyloxy-3 exo bicyclo[2.2.1]heptane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:77085-45-1 SDS

77085-45-1Downstream Products

77085-45-1Relevant academic research and scientific papers

ACTION DU N-BROMOSUCCINIMIDE SUR LES DIOXOLANNES, INTERMEDIAIRES REACTIONNELS

Bazbouz, Akram,Christol, Henri,Coste, Jacques,Pietrasanta, Francine,Plenat, Francoise

, p. 2757 - 2763 (2007/10/02)

1,3-Dioxolan-2-ylium ion intermediates formed by reaction of bromine or NBS on 4-syn-aryl-3,5-dioxa-tricyclo2,6>decanes have been isolated. 2-Succinimido-1,3-dioxolanes have been prepared for the first time.

ACTION DU N-BROMOSUCCINIMIDE SUR LES DIOXOLANNES EN SERIE BICYCLOHEPTANIQUE. LIMITATION DES TRANSPOSITIONS DE WAGNER-MEERWEIN

Bazbouz, Akram,Christol, Henri,Coste, Jacques,Plenat, Francoise

, p. 2745 - 2755 (2007/10/02)

Vicinal benzoyloxy-trans-bicycloheptanic bromhydrins, otherwise difficult to obtain are formed from N-bromosuccinimide and norbornanes bearing a 2-aryl-1,3 dioxolane skeleton.The greater stability of the intermediate dioxolenium ion reduces the tendency towards both Wagner-Meerwein rearrangement and neighbouring group participation by chlorine, processes usually observed when a less stable intermediate is involved.Nevertheless, methoxycarbonyl neighbouring group participation and Wagner-Meerwein rearrangement occur in methoxycarbonylbicycloheptane and in a bornanic compound respectively.

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