77085-84-8Relevant academic research and scientific papers
REGIOSPECIFIC ALLYLATION OF ACETALS WITH ALLYLSILANES CATALYZED BY IODOTRIMETHYLSILANE. SYNTHESIS OF HOMOALLYLETHERS
Sakurai, Hideki,Sasaki, Koshi,Hosomi, Akira
, p. 745 - 748 (2007/10/02)
Allylation of acetals with allylsilanes is catalyzed by iodotrimethylsilane to give the corresponding homoallyl ethers, with regiospecific transposition of the allyl group.
PENTADIENYLSILANES AS NEW REAGENTS OF THE SITESELECTIVE DIENYLMETHYLATION OF ELECTROPHILES PROMOTED BY A LEWIS ACID
Hosomi, Akira,Saito, Masaki,Sakurai, Hideki
, p. 3783 - 3786 (2007/10/02)
(2,4-Pentadienyl)- and (2,4-hexadienyl)trimethylsilanes, prepared from the corresponding pentadienylpotassiums and trimethylchlorosilane, react smoothly with various electrophiles such as acetals, aldehydes and acid halides to give pentadienylation produc
REACTIVITY OF SOME α- AND α,γ - UNSATURATED SILANES TOWARDS ACETALS IN THE PRESENCE OF A LEWIS ACID.
Pornet, Jacques
, p. 2049 - 2050 (2007/10/02)
α- and α,γ-unsaturared silanes undergo titanium tetrachloride-induced alkylation of acetals.
