77097-07-5Relevant academic research and scientific papers
Cyclopalladated arylsulfides and sulfoxides: Synthesis, characterization and reactivity toward m-chloroperbenzoic acid
Bhawmick, Rupa,Bandyopadhyay, Pinaki
, p. 2923 - 2926 (2008/10/09)
A number of stable di-μ-halogeno-bridged cyclopalladated complexes [Pd2L2Cl2] have been synthesized (where L = arylsulfides and their corresponding sulfoxides). The cyclopalladated compounds have been characterized on the basis of elemental analysis and spectroscopic (IR, UV-vis, and 1H and 13C NMR) data. Regioselective aromatic metaloxylation (Pd-Ar→Pd-O-Ar) or di-μ-halogeno-bridged cyclopalladated complexes occur with m-chloroperbenzoic acid at room temperature without any oxidation of sulfur atoms. Copyright
