77100-89-1Relevant academic research and scientific papers
One-pot synthesis of α-bromoesters and ketones from β-ketoesters and diketones using supported reagents system
Aoyama, Tadashi,Takido, Toshio,Kodomari, Mitsuo
, p. 1873 - 1876 (2004)
A simple and efficient method has been developed for the synthesis of α-bromoesters and ketones from β-ketoesters and diketones in one pot using a supported reagents system, CuBr2/Al2O 3-Na2CO3/Al2O3, in which β-ketoester reacts first with CuBr2/Al2O3 and the product, α-bromo-β-ketoester, reacts with Na 2CO3/Al2O3 to give the final product, α-bromoesters in good yields.
THE CUPROUS CHLORIDE CATALYZED ADDITION OF HALOGEN COMPOUNDS TO OLEFINS UNDER PHOTO-IRRADIATION
Mitani, Michiharu,Nakayama, Masao,Koyama, Kikuhiko
, p. 4457 - 4460 (2007/10/02)
The addition of organic halogen compounds to olefins in the presence of cuprous chloride under U.V. irradiation gave 1:1 adducts.
