7712-37-0

Basic information

• Product Name: Cyclohexanone, 5-(1-hydroxy-1-methylethyl)-2-methyl-
• CAS NO: 7712-37-0
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Mol File: 7712-37-0.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 5-(1-hydroxy-1-methylethyl)-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 5-(1-hydroxy-1-methylethyl)-2-methyl-(7712-37-0)
• EPA Substance Registry System: Cyclohexanone, 5-(1-hydroxy-1-methylethyl)-2-methyl-(7712-37-0)

Safety Data

• Hazardous Substances Data: 7712-37-0(Hazardous Substances Data)

Upstream product

• 58506-23-3 p-menthane-2,8-diol 
• 22567-21-1 (1S,2S,5S)-5-isopropenyl-2-methylcyclohexan-1-ol 
• 38235-58-4 trans-sobrerol 
• 75250-57-6 6-methyl-3-(2-methyloxiranyl)cyclohexanone 
• 64-17-5 ethanol 
• 75269-09-9 5-(1-hydroxy-1-methyl-2-phenyltelluroethyl)-2-methylcyclohexanone 
• 56423-45-1 2-methyl-5-(1-methyl-1-oxiranyl)-2-cyclohexen-1-one 
• 454-77-3 1(S)-5(S)-(+)-cis-sobrerol 
• 5655-36-7 (1R,2S,4S)-p-menthane-2,8-diol 
• 5655-36-7 (1R,2R,4S)-p-menthane-2,8-diol 
• 19956-45-7 (1S:2R:4S)-p-menthanediol-(2.8) 
• 160399-93-9 (1S:2S:4S)-p-menthanediol-(2.8) 

Downstream Products

• 499-70-7 carvomenthone 
• 23733-68-8 p-menth-3-en-2-one 

Relevant articles and documents

Al-NiCl(2°)6H2O-THF: A new, mild and neutral system for selective reduction of organic functional groups

A mild and neutral reducing system consisting of Al-NiCl(2°)6H2O-THF has been developed and reacted with a series of organic compounds containing different functional groups in order to evaluate its synthetic utility. It was observed that this system very efficiently reduces the α-enones to the saturated ketones, aromatic aldehydes and ketones to the corresponding alcohols, nitriles and nitroarenes to amines, acid anhydrides and acid chlorides to aldehydes, disulphides to thiols and epoxides to the corresponding alcohols. On the other hand isolated double bonds, carboxylic acids, esters, lactones, primary, benzyl and allyl halides, aliphatic aldehydes and ketones and aliphatic nitro compounds were found to remain inert to this system. Furthermore, the reducing properties of Al-NiCl(2°)6H2O in several other organic solvents were also studied.

Organic Tellurium and Selenium Chemistry. Reduction of Tellurides, Selenides, and Selenoacetals with Triphenyltin Hydride

Preparative and mechanistic details are described for the conversion of selenides into hydrocarbons RH> by heating with triphenyltin hydride at about 120 deg C.The process has been extended to selenoacetals in a form that constitutes a reduction methods for carbonyl compounds RR'C(SePh)2 -> RR'CH2>.Selective reduction of selenoacetals in the presence of thioacetals is possible.Cold-labeled species can be prepared by using triphenyltin deuteride.Tellurides are available easily without problems arising from exposure to air provided that the work is done in a photographic darkroom equipped with a red safety light.These tellurides, as well as the corresponding dichlorides , are reduced under very mild conditions (25-80 deg C) by triphenyltin hydride.The selenium- and tellurium-based chemistry has been used for the unusual process of reducing an epoxide in the presence of a ketone carbonyl.