77120-90-2

Basic information

• Product Name: 2-Pentenedioic acid, 3-[(phenylmethyl)amino]-, diethyl ester
• CAS NO: 77120-90-2
• Molecular Formula: C16H21NO4
• Molecular Weight: 291.347
• Mol File: 77120-90-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Pentenedioic acid, 3-[(phenylmethyl)amino]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentenedioic acid, 3-[(phenylmethyl)amino]-, diethyl ester(77120-90-2)
• EPA Substance Registry System: 2-Pentenedioic acid, 3-[(phenylmethyl)amino]-, diethyl ester(77120-90-2)

Safety Data

• Hazardous Substances Data: 77120-90-2(Hazardous Substances Data)

Upstream product

• 105-50-0 diethyl 1,3-acetonedicarboxylate 
• 100-46-9 benzylamine 

Downstream Products

• 77120-93-5 (2R,3R,4S)-4-Benzylamino-2-methyl-6-oxo-tetrahydro-pyran-3-carboxylic acid; hydrochloride 
• 77120-92-4 (2R,3S)-3-Benzylamino-2-((R)-1-hydroxy-ethyl)-pentanedioic acid diethyl ester 
• 77120-91-3 (E)-2-Acetyl-3-benzylamino-pent-2-enedioic acid diethyl ester 

Relevant articles and documents

A PRACTICAL SYNTHESIS OF (+/-)-THIENAMYCIN

An efficient and operationally simply synthesis of (+/-)-thienamycin is described.

Herbicidal (2 or 6)-fluoroalkyl-4-amino pyridine derivatives

Disclosed herein are 3,5-pyridinedicarboxylic acid derivatives having heteroatom substitution at the 4 position which are useful as herbicides and herbicide precursors.

Intermediate for the preparation of thienamycin

Disclosed is a process for the stereocontrolled total synthesis of thienamycin from acetone dicarboxylate via intermediate II: STR1 wherein R is a readily removable carboxyl protecting group.