77194-99-1

Upstream product

• 4547-02-8 7-chloro-1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-thione 
• 77175-99-6 N-(7-Chlor-5-phenyl-3H-1,4-benzodiazepin-2-yl)-N-methylhydroxylamin 
• 530-62-1 1,1'-carbonyldiimidazole 

Relevant academic research and scientific papers

The Oxidoreductive 1,3-Rearrangement of 3H-1,4-Benzodiazepines with Semicyclic Hydroxyamidine Structure to 2-Alkylamino-3-acyloxy-3H-1,4-benzodiazepines

On treatment of N-alkyl-N-(3H-1,4-benzodiazepin-2-yl)-hydroxylamines with carboxylic anhydrides or chlorides an oxidoreductive rearrangement is observed in the presence of protons that leads to 1,4-benzodiazepines bearing the acylated hydroxylaminic oxyge