77196-38-4Relevant academic research and scientific papers
Synthesis and X-Ray Analysis of 2,3,5,6,11-Pentaoxabicycloundecanes
Miura, Masahiro,Ikegami, Akio,Nojima, Masatomo,Kusabayashi, Shigekazu,McCullough, Kevin J.,Walkinshaw, Malcolm D.
, p. 1657 - 1664 (2007/10/02)
The reactions of bicyclic ozonides and aldehyde- or ketone-derived peroxides, performed or generated in situ, in the presence of chlorosulphonic acid afford the corresponding 2,3,5,6,11-pentaoxabicycloundecanes.In addition, 1,2,4,5-tetraoxans are often isolated from the product mixture.Mechanisms are proposed to account for the observed peroxidic products.An X-ray analysis of the crystalline product (4b) confirms the general structure and reveals that it is solely the exo-isomer.
Synthesis of 1,4-Disubstituted (or 1,4,4-Trisubstituted) 2,3,5,6,11-Pentaoxabicycloundecanes
Miura, Masahiro,Ikegami, Akio,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 1279 - 1281 (2007/10/02)
The reaction of a mixture of bicyclic ozonides (trioxolans), carbonyl compounds, and hydrogen peroxide in the presence of catalytic amounts of chlorosulphonic acid gives the corresponding 2,3,5,6,11-pentaoxabicycloundecanes in 3-35percent yield.
