77198-20-0Relevant academic research and scientific papers
Microwave-Assisted Cp*CoIII-Catalyzed C-H Activation/Double C-N Bond Formation Reactions to Thiadiazine 1-Oxides
Huang, Jiapian,Huang, Yangfei,Wang, Tao,Huang, Qin,Wang, Zhihua,Chen, Zhiyuan
, p. 1128 - 1131 (2017)
A microwave-assisted, Cp*CoIII-catalyzed direct C-H activation/double C-N bond formation reaction of simple NH-sulfoximines with 1,4,2-dioxazol-5-ones to produce diverse thiadiazine-1-oxides is reported. The reaction tolerates a broad range of functional groups under external oxidant-free conditions and only releases CO2 and H2O as the sole byproducts. The preliminary mechanistic studies revealed an electrophilic metalation pathway is likely involved in the reaction.
DERIVATIVES OF SULFONIMIDIC ACIDS. REACTION OF ARENSULFINYL CHLORIDES WITH N-CHLORO-N'-PHENYLBENZAMIDINE
Slyasarenko, E. I.,Pel'kis, N. P.,Levchenko, E. S.
, p. 1832 - 1835 (2007/10/02)
In reaction with N-chloro-N'-phenylbenzamidine arensulfinyl chlorides are iminated with the formation of N-(N'-phenylbenzimidoyl)arenesulfonimidoyl chlorides.The reaction of the latter with amine and phenolates gave the corresponding derivatives of N-(N'-
