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5-Methyl-benzocycloheptene is a chemical compound with the molecular formula C14H14. It is a derivative of benzocycloheptene, featuring a methyl group (CH3) attached to the 5th carbon atom of the benzene ring. 5-methyl-benzocycloheptene is an aromatic hydrocarbon with a seven-membered cyclic structure, consisting of a benzene ring fused to a cycloheptene ring. 5-Methyl-benzocycloheptene is known for its unique chemical properties and potential applications in various fields, such as pharmaceuticals, agrochemicals, and materials science. Due to its complex structure, it is often synthesized through advanced chemical reactions and is not commonly found in nature.

772-05-4

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772-05-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 772-05-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,7 and 2 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 772-05:
(5*7)+(4*7)+(3*2)+(2*0)+(1*5)=74
74 % 10 = 4
So 772-05-4 is a valid CAS Registry Number.

772-05-4Downstream Products

772-05-4Relevant articles and documents

Generation of cycloheptyne during the solvolysis of cyclohexylidenemethyliodonium salt in the presence of base

Fujita, Morifumi,Ihara, Kenji,Kim, Wan Hyeok,Okuyama, Tadashi

, p. 1849 - 1855 (2003)

Solvolysis of 4-methylcyclohexylidenemethyl(phenyl)iodonium tetrafluoroborate (1) and its R isomer (69% ee) was carried out in 2,2,2-trifluoroethanol (TFE) and 1,1,1,3,3,3-hexafluoropropan-2-ol (HFP) in the presence of bases such as acetate, pyridine, triethylamine, and alkoxide. The reaction is much faster in TFE than in HFP. Products in TFE include solely un-rearranged (racemized) enol ether 2 together with iodobenzene, while the main product in HFP is ring-expanded (partially racemized) 1-alkoxycycloheptene 3. Results show that 2 is formed via α-elimination with alkylidenecarbene as an intermediate, while the reaction in HFP to give 3 involves a cycloheptyne intermediate that is mostly derived from an intermediate cyclohept-1-enyl cation via the E1-type pathway.

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