772-12-3

Upstream product

• 95-82-9 2,5 dichloroaniline 
• 540-72-7 sodium thiocyanide 
• 1147550-11-5 ammonium thiocyanate 

Downstream Products

• 15178-57-1 4-amino-2,5-dichlorothiophenol 
• 56311-71-8 2',5'-Dichlor-4'-thiocyanato(4-chlorphenoxy)acetanilid 
• 56311-70-7 2',5'-Dichlor-4'-thiocyanatophenoxyacetanilid 
• 56376-60-4 2-Brom-2',5'-dichlor-4'-thiocyanatopropionanilid 

Relevant academic research and scientific papers

Microwave-assisted neat reaction technology for regioselective thiocyanation of substituted anilines and indoles in solid media

An efficient and solvent -free approach for regioselective thiocyanation of various substituted anilines and indoles is described. The reaction performed both on and off the alumina surface under microwave conditions. Microwave irradiation reactions under

INSECTICIDAL AND ACARICIDAL ANILINOTRIAZOLES

Novel anilinotriazoles of the formula ( I ) wherein R1 represents haloalkyl; R2 represents alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, or phenylalkyl that may be optionally substituted; R3 represents hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, phenylalkyl that may be optionally substituted, cyanoalkyl, (alkoxycarbonyl)(alkoxy)alkyl, (alkoxycarbonyl)(alkylthio)alkyl, alkylcarbonyl, cycloalkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, alkylthioalkylcarbonyl, phenylcarbonyl that may be optionally substituted, benzylcarbonyl that may be optionally substituted, alkoxycarbonyl, alkylthiocarbonyl, alkylsulfonyl, benzenesulfonyl that may be optionally substituted, or dialkylaminosulfonyl; R4 represents halogen or haloalkyl; R5 represents haloalkyl; R6 represents halogen, alkyl, haloalkyl, haloalkoxy, haloalkylthio, cyano or nitro; m represents 0, 1 or 2; and n represents 0, 1 or 2, and the use of the new compounds as insecticides and acaricides.

Ferric(III) chloride-promoted electrophilic thiocyanation of aromatic and heteroaromatic compounds

Indoles, oxindoles and aromatic amino compounds undergo smooth thiocyanation with ammonium thiocyanate in the presence of anhydrous FeCl 3 in dichloromethane under mild conditions to afford the corresponding 3-indolyl and 4-aryl thiocyanates, respectively, in high yields with excellent selectivity. The use of ferric chloride makes it quite simple, more convenient and practical. This new method offers several advantages such as high conversions, cleaner reaction profiles, short reaction times, and the use of inexpensive and readily available catalyst. Georg Thieme Verlag Stuttgart.

Substituted-4-alkylthioalkane-sulfonanilides and operatives

Alkane- and monohaloalkane-sulfonanilides substituted in the para position by alkylthio, alkylsulfinyl and alkylsulfonyl groups and additionally substituted by halogen and optionally by trifluoromethyl and agriculturally acceptable salts thereof are useful herbicides.