772-52-1Relevant academic research and scientific papers
Highly chemoselective difluoromethylative homologation of iso(thio)cyanates: Expeditious access to unprecedented α,α-difluoro(thio)amides
Miele, Margherita,D'Orsi, Rosarita,Sridharan, Vellaisamy,Holzer, Wolfgang,Pace, Vittorio
, p. 12960 - 12963 (2019)
The new motif-α,α-difluoromethyl thioamide-has been assembled starting from isothiocyanate (as thioamide precursor) and a formal difluoromethyl-carbanion generated from commercially available TMSCHF2. Upon proper activation of this reagent with
