7722-71-6Relevant academic research and scientific papers
The oxorhenium(VII)-catalyzed direct condensation of phosphoric acid with an alcohol
Sakakura, Akira,Katsukawa, Mikimoto,Ishihara, Kazuaki
, p. 1423 - 1426 (2008/03/15)
(Chemical Equation Presented) Come together ... over Re: Oxorhenium-(VII) complexes catalyze the direct condensation of phosphoric acid with an alcohol to selectively give the corresponding phosphoric acid monoester on a 2-100-mmol scale (see scheme). This method should be useful for the industrially important synthesis of phosphoric acid monoesters.
Selective synthesis of phosphate monoesters by dehydrative condensation of phosphoric acid and alcohols promoted by nucleophilic bases
Sakakura, Akira,Katsukawa, Mikimoto,Ishihara, Kazuaki
, p. 1999 - 2002 (2007/10/03)
(Chemical Equation Presented) Phosphate monoesters are synthesized from a mixture of phosphoric acid (1 or 2 equiv) and alcohols (1 equiv) in the presence of tributylamine. The reaction is promoted by nucleophilic bases such as N-alkylimidazole and 4-(N,N-dialkylamino)pyridine. 2′,3′-I- Isopropylidene ribonucleosides are selectively converted to their 5′-monophosphates without the protection of amino groups in nucleobases.
