77222-54-9

Basic information

• Product Name: 2-Methoxymethyl-3-phenyl-pent-4-enoic acid methyl ester
• Synonyms: 2-Methoxymethyl-3-phenyl-pent-4-enoic acid methyl ester
• CAS NO: 77222-54-9
• Molecular Weight: 234.295
• Mol File: 77222-54-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Methoxymethyl-3-phenyl-pent-4-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methoxymethyl-3-phenyl-pent-4-enoic acid methyl ester(77222-54-9)
• EPA Substance Registry System: 2-Methoxymethyl-3-phenyl-pent-4-enoic acid methyl ester(77222-54-9)

Safety Data

• Hazardous Substances Data: 77222-54-9(Hazardous Substances Data)

Upstream product

• 77197-59-2 Trimethyl-β-(methoxy) ortho propionate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 73421-20-2 2-methylene-3-phenyl-4-pentenoate de methyle 

Relevant articles and documents

CLAISEN ORTHO ESTER REARRANGEMENT WITH TRIMETHYL β-(METHOXY)ORTOPROPIONATE: A TERMALLY STABLE SYNTHON FOR THE PREPARATION OF METHYL α-SUBSTITUTED ACRYLATES

Trimethyl β-(methoxy)ortopropionate, a compound which is thermally stable at 190 deg C for proplonged times, may be utilized as a synthon for the preparation of methyl α-substituted acrylates via Claisen ortho ester rearrangement with allylic alcohols followed by β-elimination of methanol with base.