77246-07-2Relevant academic research and scientific papers
ANIONIC -CYCLOADDITION OF DITHIOBENZOATE ION AT ACTIVATED MULTIPLE BONDS
Drozd, V. N.,Popova, O. A.,Vyazgin, A. S.,Dmitriev, L. B.
, p. 750 - 754 (2007/10/02)
The dithiobenzoate anion (in the form of the triethylammonium salt) reacts with activated acetylenes by a mechanism of anionic -cycloaddition with the formation of 3-phenyl-1,3-dithioles.With an activated alkene (dimethyl fumarate) the acyclic product from Michael addition of dithiobenzoic acid at the double bond is formed in addition to the corresponding 1,3-dithioles.
