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(2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin is a complex brominated benzoxepin derivative with a chiral center at the 2-position, featuring multiple methyl groups and a bromomethyl substituent. (2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin exhibits a unique molecular structure that endows it with high reactivity and potential applications in various chemical processes.

77249-85-5

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77249-85-5 Usage

Uses

Used in Organic Synthesis:
(2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin is used as a reactive intermediate for the synthesis of various organic compounds. Its unique structure and reactivity make it a valuable building block for the development of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Research and Development:
(2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin serves as an interesting target for research in the field of organic chemistry, particularly in the study of chiral molecules and their properties. Its complex structure and potential reactivity provide opportunities for exploring novel reaction mechanisms and developing innovative synthetic methods.
Used in Chemical Reactions:
(2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin is utilized in various chemical reactions, such as cross-coupling, substitution, and cyclization processes. Its presence of bromine and multiple methyl groups allows for selective functionalization and the formation of diverse molecular architectures.
Used in Pharmaceutical Industry:
As a chiral molecule with a complex structure, (2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin can be employed as a key intermediate in the synthesis of enantioselective pharmaceutical agents. Its unique stereochemistry may contribute to the development of novel drugs with improved efficacy and selectivity.
Used in Material Science:
(2R)-7β-Bromo-2-(bromomethyl)-2,5,5aα,6,7,8,9,9a-octahydro-3,6,6,9aβ-tetramethyl-1-benzoxepin's reactivity and structural features make it a potential candidate for the development of new materials with specific properties, such as polymers, coatings, or advanced materials for various applications in industries like electronics, automotive, and aerospace.

Check Digit Verification of cas no

The CAS Registry Mumber 77249-85-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,2,4 and 9 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 77249-85:
(7*7)+(6*7)+(5*2)+(4*4)+(3*9)+(2*8)+(1*5)=165
165 % 10 = 5
So 77249-85-5 is a valid CAS Registry Number.

77249-85-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (+)-palisadin B

1.2 Other means of identification

Product number -
Other names (2R,5AS,7S,9AS)-7-BROMO-2-(BROMOMETHYL)-2,5,5A,6,7,8,9,9A-OCTAHYDRO-3,6,6,9A-TETRAMETHYL-1-BENZOXEPIN

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:77249-85-5 SDS

77249-85-5Downstream Products

77249-85-5Relevant academic research and scientific papers

Novel stereocontrolled approach to syn- and anti-oxepene-cyclogeranyl trans-fused polycyclic systems: Asymmetric total synthesis of (-)-Aplysistatin, (+)-Palisadin A, (+)-Palisadin B, (+)-12-hydroxy-Palisadin B, and the AB ring system of adociasulfate-2 a

Cooladouros, Elias A.,Vidali, Veroniki P.

, p. 3822 - 3835 (2007/10/03)

A new stereocontrolled method for the formation of trans-anti cyclogeranyl-oxepene systems is described. The demanding stereochemistry is secured by stereoselective coupling of a cyclogeranyl tertiary alcohol with a 1,2-unsymmetrically substituted epoxide

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