77250-62-5Relevant academic research and scientific papers
Chiral Mercaptoaryl-oxazolines as Ligands in Enantioselective Copper-Catalyzed 1,4-Additions of Grignard Reagents to Enones
Zhou, Qi-Lin,Pfaltz, Andreas
, p. 4467 - 4478 (1994)
A series of chiral enantiomerically pure mercaptoaryl-oxazolines has been synthesized.Copper(I) thiolate complexes derived from these ligands proved to be efficient catalysts for the 1,4-addition of Grignard reagents to cyclic enones.Enantioselectivities
2-OXAZOLINES FROM AMIDES VIA IMIDATES
Meyers, A. I.,Hanagan, Mary Ann,Mazzu, Arthur L.
, p. 361 - 367 (2007/10/02)
Chiral oxazolines useful in asymmetric synthesis of o-substituted phthalides and benzoic acids are readily prepared from the benzamides via their imino ethers.
