77287-19-5Relevant academic research and scientific papers
An Unexpected Intramolecular Photoreaction of a Hexachlorooctahydrodimethanonaphthaline
Parlar, H.,Inanici, Y.
, p. 125 - 126 (2007/10/02)
Photoreactions of 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-endo,endo-5,8-dimethano-naphthaline (1) were studied in acetone with wavelengths above 290 nm.With the help of column chromatography an unusual isomerisation product (4) could be isolated, whose structure was established by spectral data obtained by mass spectrometry infrared spectroscopy, 1H and 13C nuclear magnetic resonance measurements. - Keywords: Photochemistry, Isomerisation Reactions, Hexachlorooctahydrodimethanonaphthalines
