77300-02-8

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2-carboxylic acid, 6-(benzoyloxy)-5-bromo-, methyl ester, (2-exo,5-endo,6-exo)-
• CAS NO: 77300-02-8
• Molecular Formula: C16H17BrO4
• Mol File: 77300-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2-carboxylic acid, 6-(benzoyloxy)-5-bromo-, methyl ester, (2-exo,5-endo,6-exo)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2-carboxylic acid, 6-(benzoyloxy)-5-bromo-, methyl ester, (2-exo,5-endo,6-exo)-(77300-02-8)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2-carboxylic acid, 6-(benzoyloxy)-5-bromo-, methyl ester, (2-exo,5-endo,6-exo)-(77300-02-8)

Safety Data

• Hazardous Substances Data: 77300-02-8(Hazardous Substances Data)

Upstream product

• 68763-55-3 dioxa-3,5 exo phenyl-4 syn carbomethoxy-8 exo tricyclo <5.2.1.0^2,6> decane 

Downstream Products

• 22664-23-9 carbomethoxy-2 exo hydroxy-6 exo bicyclo <2.2.1> heptane 

Relevant articles and documents

ACTION DU N-BROMOSUCCINIMIDE SUR LES DIOXOLANNES EN SERIE BICYCLOHEPTANIQUE. LIMITATION DES TRANSPOSITIONS DE WAGNER-MEERWEIN

Vicinal benzoyloxy-trans-bicycloheptanic bromhydrins, otherwise difficult to obtain are formed from N-bromosuccinimide and norbornanes bearing a 2-aryl-1,3 dioxolane skeleton.The greater stability of the intermediate dioxolenium ion reduces the tendency towards both Wagner-Meerwein rearrangement and neighbouring group participation by chlorine, processes usually observed when a less stable intermediate is involved.Nevertheless, methoxycarbonyl neighbouring group participation and Wagner-Meerwein rearrangement occur in methoxycarbonylbicycloheptane and in a bornanic compound respectively.