77301-89-4

Upstream product

• 62897-30-7 1,1,3,4,4,4-Hexachlor-1-buten 
• 18803-44-6 sodium p-chlorothiophenolate 
• 62897-29-4 1,1,1,4,4,4-hexachloro-but-2-ene 
• 62897-26-1 tetrakis(4-chlor-phenylthio)butatrien 
• 106-54-7 p-Chlorothiophenol 
• 77301-83-8 1,2-Dichlor-1,4,4-tris(4-chlor-phenylthio)-1,3-butadien 
• 77301-85-0 1-Chlor-1,4,4-tris(4-chlorphenylthio)butatrien 

Downstream Products

• 76202-66-9 2,3-Dichlor-1,1,4,4-tetrakis(4-chlor-phenylthio)-1,3-butadien 

Relevant academic research and scientific papers

New thiosubstituted butadiene and butenyne compounds from hexachloro-butenes and thiols

2,3-Di-H-butene compound 1 gave compounds 3a-f, 4a, 4e, and 5a-d in the presence of thiols 2a-f and Et3N (or NaOH). Compound 7e was obtained from the reaction of 1,3-Di-H-butene 6 with naphthylthiol in DMF. In the presence of NaOH, compound 6 a

Reactions of Polychloro-1,3-butadienes and Polychlorobutenes with Thiolates

On treatment of perchlorobutadiene (1), of the pentachlorobutadienes 10 and 18, or of the hexachlorobutenes 21, 25, and 32 with thiolates in DMSO a very fast and extensive replacement of chlorine is observed even at room temperature.The reactions 1 -> 7,