77303-72-1Relevant academic research and scientific papers
PHOTOLYSIS AND THERMOLYSIS OF 3-DIAZOTHIOCHROMAN-4-ONE AND RELATED COMPOUNDS
Tamura, Yasumitsu,Ikeda, Hiroyuki,Mukai, Chisato,Bayomi, Said Mohamad M.,Ikeda, Masazumi
, p. 3430 - 3433 (2007/10/02)
The photochemical and thermal reactions of 3-diazothiochroman-4-one (2a), 3-diazochroman-4-one (2b), 3-diazo-1-methyl-1,2,3,4-tetrahydroquinolin-4-one (2c), and 2-diazo-1-tetralone (2d) were investigated.Wolff rearrangement was observed with 2a, 2c, and 2d only under photolytic conditions.In the case of 2a, migration of the thioether group competed with the above reaction.Keywords - tosyl azide; α-diazoketone; episulfonium ylide; carbene; Wolff rearrangement; participation of thioether; dimerization
