77304-55-3Relevant academic research and scientific papers
Electrocatalytic Oxidant-Free Dehydrogenative C?H/S?H Cross-Coupling
Wang, Pan,Tang, Shan,Huang, Pengfei,Lei, Aiwen
, p. 3009 - 3013 (2017)
An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C?H/S?H cross-coupling. This method enabled C?S bond formation under catalyst- and oxidant-free conditions. Under undivided electrolysis conditions, various aryl/heteroaryl thiols and electron-rich arenes afforded the C?S bond-formation products in 24–99 % yield. A preliminary mechanistic study indicated that the generation of aryl radical cation intermediates is key to the success of this transformation.
