773079-62-2Relevant academic research and scientific papers
A new and efficient method for o-quinone methide intermediate generation: Application to the biomimetic synthesis of the benzopyran derived natural products (±)-lucidene and (±)-alboatrin
Rodriguez, Raphael,Moses, John E.,Adlington, Robert M.,Baldwin, Jack E.
, p. 3488 - 3495 (2007/10/03)
Lucidene and alboatrin are complex benzopyran derived natural products. A key step in their biogenesis may involve a hetero Diels-Alder cycloaddition between an o-quinone methide intermediate with a simple, or activated tri-substituted olefin. Experimental evidence is provided to support this hypothesis, with the biomimetic synthesis of both (±)-lucidene and (±)-alboatrin successfully achieved using a new and efficient method for o-quinone methide generation. The Royal Society of Chemistry 2005.
A new and efficient method for o-quinone methide intermediate generation: Application to the biomimetic synthesis of (±)-Alboatrin
Rodriguez, Raphael,Adlington, Robert M.,Moses, John E.,Cowley, Andrew,Baldwin, Jack E.
, p. 3617 - 3619 (2007/10/03)
(Chemical Equation Presented) A new and efficient method for o-quinone methide intermediate generation from o-methyleneacetoxy-phenols has been developed and applied to the biomimetic synthesis of (±)-Alboatrin.
