773094-62-5

Upstream product

• 273-13-2 benzo[1,2,5]thiadiazole 
• 106-41-2 4-bromo-phenol 
• 111-83-1 1-bromo-octane 
• 96693-05-9 1-bromo-4-octyloxybenzene 

Downstream Products

• 1021849-53-5 2,3-bis(4-octyloxyphenyl)-5,8-bis(5'-bromo-dithien-2-ly)quinoxaline 
• 1358763-34-4 2,3-bis(4-octyloxyphenyl)-5,8-bis(4'-hexyl-2,2'-bithiophene-5-ly)quinoxaline 
• 1358763-36-6 2,3-bis(4-octyloxyphenyl)-5,8-bis(5'-bromo-4'-hexyl-2,2'-bithiophene-5-ly)quinoxaline 
• 1263039-56-0 5,8-bis(hexylthiophen-2-yl)-2,3-bis(4-(octyloxy)phenyl)quinoxaline 
• 1345823-85-9 2,3-bis[4-(octyloxy)phenyl]-5,8-diethynylquinoxaline 
• 1345823-84-8 2,3-bis[4-(octyloxy)phenyl]-5,8-bis[(trimethylsilyl)ethynyl]quinoxaline 
• 1304514-33-7 C₄₈H₆₈B₂N₂O₆ 
• 1304514-34-8 C₆₀H₈₂N₂O₂S₂ 

Relevant academic research and scientific papers

Synthesis and characterization of quinoxaline-based thiophene copolymers as photoactive layers in organic photovoltaic cells

A series of new quinoxaline-based thiophene copolymers (PQx2T, PQx4T, and PQx6T) was synthesized via Yamamoto and Stille coupling reactions. The M ws of PQx2T, PQx4T, and PQx6T were found to be 20,000, 12,000, and 29,000, with polydispersity in

Synthesis and photovoltaic properties of quinoxaline-based alternating copolymers for high-efficiency bulk-heterojunction polymer solar cells

A series of quinoxaline-based copolymers, namely, poly[N-9″- heptadecanyl-2,7-carbazole-alt-5,5-(5′,8′-di-2-thienylquinoxaline)] (P1), poly[N-9″-heptadecanyl-2,7-carbazole-alt-5,5-(5′,8′-di- 2-thienyl-2,3-bis(4-octyloxyl)phenyl)quinoxaline] (P2), and poly

Synthesis and characterization of fully conjugated donor-acceptor-donor triblock copolymers

A synthetic approach is established to provide a monofunctional telechelic poly(3-octylthiophene) (P3OT) bearing a single bromine-substituted end group that is of potential use in the preparation of well-defined block copolymers. Telechelic P3OT was prepared via a chain growth process by a catalyst-transfer condensation polymerization (CTCP) of 5-bromo-4-octyl-2-thienylmagnesium iodide initiated by a phenylnickel(II) initiator. Optimization of the conditions for quenching the reaction allowed for the installation an α-bromo functionality at the terminus of the polymer. We demonstrate the utility of this well-defined monofunctional polymer, Ph-P3OT-Br, by coupling it to a poly(quinoxaline) (PQ) bearing boronate ester end groups to provided a new class of donor-acceptor-donor (D-A-D) triblock copolymers. The formation of the triblock copolymers was confirmed by gel-permeation chromatography (GPC) and 1H NMR spectroscopy. The optical properties of the polymers were investigated using UV-visible absorption and fluorescence spectroscopy. Efficient quenching of the fluorescence from the individual blocks of the triblock copolymers is consistent with the occurrence of electron transfer. AFM images illustrate a nanoscale phase separation of the electron-rich P3OT and electron-poor PQ blocks.