773121-57-6

Basic information

• Product Name: Silane, (1-ethyl-1-butenyl)dimethylphenyl-
• CAS NO: 773121-57-6
• Molecular Formula: C14H22Si
• Molecular Weight: 218.414
• Mol File: 773121-57-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (1-ethyl-1-butenyl)dimethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1-ethyl-1-butenyl)dimethylphenyl-(773121-57-6)
• EPA Substance Registry System: Silane, (1-ethyl-1-butenyl)dimethylphenyl-(773121-57-6)

Safety Data

• Hazardous Substances Data: 773121-57-6(Hazardous Substances Data)

Upstream product

• 928-49-4 hex-3-yne 
• 766-77-8 Dimethylphenylsilane 
• 586-75-4 4-chlorobenzoyl chloride 

Relevant articles and documents

Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying I-Bond Migration

We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying I-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine ligand is the key intermediate and (ii) I-bond migration occurs prior to hydrosilylation. The cascade process selectively furnishes terminal branched allylsilanes under mild conditions.

Chemoselective ruthenium-catalyzed reduction of acid chlorides to aldehydes with dimethylphenylsilane

A variety of aromatic and alkyl acid chlorides can be selectively converted into aldehydes using dimethylphenyl silane (HSiMe2Ph) as the reducing reagent in the presence of the cationic ruthenium catalyst {Cp[(i-Pr)3P]Ru(NCMe)2}+ [PF6] -. The reactions proceed under very mild conditions and are tolerant to many functional groups. Copyright