77317-06-7

Basic information

• Product Name: 2-(isochroman-1-yl)cyclohexanone
• Synonyms: 2-(isochroman-1-yl)cyclohexanone
• CAS NO: 77317-06-7
• Molecular Weight: 230.307
• Mol File: 77317-06-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-(isochroman-1-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(isochroman-1-yl)cyclohexanone(77317-06-7)
• EPA Substance Registry System: 2-(isochroman-1-yl)cyclohexanone(77317-06-7)

Safety Data

• Hazardous Substances Data: 77317-06-7(Hazardous Substances Data)

Upstream product

• 493-05-0 isochromane 
• 108-94-1 cyclohexanone 
• 31253-52-8 α-chloroisochroman 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 670-80-4 4-cyclohexen-1-ylmorpholine 
• 77317-07-8 2-(1-isochromanyl)-1-(4-morpholino)cyclohexene 
• 75802-22-1 1-ethoxyisochromane 

Downstream Products

• 109573-79-7 2-<2-(2-Hydroxyethyl)-benzyl>-cyclohexanone 
• 2141-42-6 1,2,3,4-tetrahydroanthracene 
• 109573-83-3 o-(2-Oxocyclohexylmethyl)-phenylacetaldehyde 

Relevant articles and documents

Visible-light induced enhancement in the multi-catalytic activity of sulfated carbon dots for aerobic carbon-carbon bond formation

The development of carbonaceous materials as metal-free catalysts integrating different types of catalysis in a single system represents a significant advance in cascade/tandem organic synthesis. Zero-dimensional carbon dots with tuneable optical properties and easily modifiable surface functionalities can be harnessed as a carbocatalyst for merging photooxidation and acid-catalyzed reactions in one pot. Herein, we explore carbon dots decorated with hydrogen sulfate groups as a photocatalyst for the dehydrogenative cross-coupling of xanthenes with ketones, arenes and 1,3-dicarbonyl compounds that showed high efficiency and selectivity under visible-light irradiation. The sulphated carbon dots demonstrate dual catalytic properties, wherein they induced the rapid photooxidation of xanthenes in the presence of molecular oxygen to form a hydroperoxy intermediate followed by coupling of nucleophiles catalysed by the acidic surface functional groups. The methodology represents an operationally simple pathway for the generation of C-C coupling products in a short reaction time with wide substrate scopes under mild conditions. The catalyst is easily separable and can be reused over multiple cycles with good efficiency.

Structurally diverse α-substituted benzopyran synthesis through a practical metal-free C(sp3)-H functionalization

A trityl ion-mediated practical C-H functionalization of a variety of benzopyrans with a wide range of nucleophiles (organoboranes and C-H molecules) at ambient temperature has been disclosed. The metal-free reaction has an excellent functional group tole

Synthesis of Carbocyclic Spiro Compounds from Isochroman Derivatives via Intramolecular Aldol Reaction

Condensation of 1-ethoxyisochromans with cyclohexanones, 1-indanone, or 1-tetralone in the presence of boron trifluoride etherate affords α-(isochroman-1-yl)-cyclic ketones.Reductive ring cleavage of the isochromanyl moiety followed by Jones oxidation yie