77326-05-7Relevant academic research and scientific papers
Kinetic Facial Selectivity in Nucleophilic Displacements at Tetracoordinate Phosphorus: Kinetics and Stereochemistry in the Reaction of Sodium Ethoxide with O,S-Dimethyl Phenylphosphonothioate
DeBruin, Kenneth E.,Tang, Chen-lan W.,Johnson, David M.,Wilde, Ronnie L.
, p. 5871 - 5879 (2007/10/02)
The reaction of ethoxide ion with O,S-dimethyl phenylphosphonothioate (1a) proceeds with competitive displacements of the methylthio and methoxy ligands.Each displacement occurs with complete inversion of configuration.The two products, ethyl methyl pheny
CHIRAL PHENYLPHOSPHONIC ESTERS, THEIR PREPARATION VIA ETHYL N- L-PROLINATE AND THEIR ABSOLUTE CONFIGURATIONS
Koizumi, Toru,Takagi, Hiroyasu,Yoshii, Eiichi
, p. 1403 - 1406 (2007/10/02)
Diastereomerically pure ethyl N--L-prolinate was prepared.From this intermediate various optically active phenylphosphonic acid derivatives have been obtained in high optical yields.Their absolute configurations have been det
