77329-76-1Relevant academic research and scientific papers
Enantioselective synthesis of thiosulfinates and of acyclic alkylidenemethylene sulfide sulfoxides
Colonna, Stefano,Pironti, Vincenza,Drabowicz, Jozef,Brebion, Franck,Fensterbank, Louis,Malacria, Max
, p. 1727 - 1730 (2005)
Enantioselectivities up to 75 % have been found in the catalytic mono-oxidation of di-tert-butyl disulfide and related compounds as well as of ketene-S,S-acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess
The first effective procedure for the direct esterification and thiolysis of sulfinic acids
Drabowicz, Jozef,Kwiatkowska, Malgorzata,Kielbasinski, Piotr
experimental part, p. 3563 - 3564 (2009/06/18)
Alkyl arenesulfinates and S-thiosulfinates are readily accessible in good yields by the reaction of sulfinic acids and alcohols or thiols, respectively, in the presence of lanthanide(III) triflates as catalysts. Georg Thieme Verlag Stuttgart · New York.
THE FIRST STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE THIOSULFINATES
Drabowicz, Jozef,Mikolajczyk, Marian
, p. 5703 - 5706 (2007/10/02)
Treatment of optically active p-toluenesulfinamides (1) with thiols (2) in the presence of trifluoroacetic acid was found to give optically active p-toluenethiosulfinates (3) with predominant inversion of configuration.Stereospecificity of this reaction v
