77329-76-1

Basic information

• Product Name: (S)-t-butyl-p-toluenethiosulfinate
• Synonyms: (S)-t-butyl-p-toluenethiosulfinate
• CAS NO: 77329-76-1
• Molecular Weight: 228.379
• Mol File: 77329-76-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (S)-t-butyl-p-toluenethiosulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-t-butyl-p-toluenethiosulfinate(77329-76-1)
• EPA Substance Registry System: (S)-t-butyl-p-toluenethiosulfinate(77329-76-1)

Safety Data

• Hazardous Substances Data: 77329-76-1(Hazardous Substances Data)

Upstream product

• 536-57-2 p-toluene sulfinic acid 
• 75-66-1 2-methylpropan-2-thiol 
• 21179-27-1 (S)-(+)-N,N,4-trimethylbenzenesulfinamide 
• 64353-47-5 (+)-(S)-N-p-tolylsulfinylpyrrolidine 
• 64258-17-9 1-(tert-butyldisulfanyl)-4-methylbenzene 

Downstream Products

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 2943-20-6 1-(tert-butyl)-2-phenyldisulfane 

Relevant articles and documents

Enantioselective synthesis of thiosulfinates and of acyclic alkylidenemethylene sulfide sulfoxides

Enantioselectivities up to 75 % have been found in the catalytic mono-oxidation of di-tert-butyl disulfide and related compounds as well as of ketene-S,S-acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess

THE FIRST STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE THIOSULFINATES

Treatment of optically active p-toluenesulfinamides (1) with thiols (2) in the presence of trifluoroacetic acid was found to give optically active p-toluenethiosulfinates (3) with predominant inversion of configuration.Stereospecificity of this reaction v

O-, S-, and N-Sulfinylations with Sulfinic Acid in the Presence of Phenyl Phosphorodichloridate and Pyridine

-