77333-20-1Relevant articles and documents
Metall-Bor-Verbindungen, 13. Zur Synthese und Reaktivitaet einiger (Trimethylstannyl)borane
Noeth, Heinrich,Schwerthoeffer, Ruediger
, p. 3056 - 3062 (2007/10/02)
The preparation of some amino(trimethylstannyl)boranes and their chemical properties are described.With Me3SnLi (Me = CH3) as a reagent only the synthesis of Me3SnB(NR2)2 (1a, b), Me3SnBCl(NR2) (2a, b), and (Me3Sn)2BNR2 (3b) was achieved.The stannylboranes Me3SnB(NR2)2 show astonishing thermal stability.Their Sn - B bonds are broken by hydrogen, the halogens, and chalcogens as well as by alcohols.HCl cleaves the B - N bond.