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Natuerlich vorkommende Terpen-Derivate, 306. Synthese eines Furansesquiterpens aus Eumorphia prostata
Bohlmann, Ferdinand,Fiedler, Lothar
, p. 227 - 231 (2007/10/02)
Starting with 5-methyl-2-cyclohexen-1-one (1) through the intermediate 4 the cyclopentene carbaldehydes 5 and 6 were synthesized.Wittig reaction led to epimeric nitriles 7 and 8, which after conversion to the aldehydes 9 and 10 on reaction with β-furyllit
