77367-78-3

Basic information

• Product Name: 3-(4-Bromo-benzyl)-2-hydroxy-cyclohepta-2,4,6-trienone
• Synonyms: 3-(4-Bromo-benzyl)-2-hydroxy-cyclohepta-2,4,6-trienone
• CAS NO: 77367-78-3
• Molecular Weight: 291.144
• Mol File: 77367-78-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(4-Bromo-benzyl)-2-hydroxy-cyclohepta-2,4,6-trienone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-Bromo-benzyl)-2-hydroxy-cyclohepta-2,4,6-trienone(77367-78-3)
• EPA Substance Registry System: 3-(4-Bromo-benzyl)-2-hydroxy-cyclohepta-2,4,6-trienone(77367-78-3)

Safety Data

• Hazardous Substances Data: 77367-78-3(Hazardous Substances Data)

Upstream product

• 77367-71-6 2-(4-bromophenylmethoxy)tropone 

Relevant articles and documents

A THERMALLY-INDUCED RADICAL REARRANGEMENT OF 2-ARYLMETHOXYTROPONES TO 3- AND 5-ARYLMETHYLTROPOLONES

2-Arylmethoxytropones, i.e., 2-benzyloxytropone, 2-(p-tolylmethoxy)tropone, 2-(4-bromophenylmethoxy)tropone, 2-(4-chlorophenylmethoxy)tropone, 2-(4-methoxyphenylmethoxy)tropone, and 2-(1-naphthylmethoxy)tropone, rearranged upon heating to the 3- and 5-arylmethyltropolones via the radical intermediates.Similarly, 5-bromo-2-(p-tolylmethoxy)tropone gave 5-bromo-3-(p-tolylmethyl)tropolone.