77387-70-3

Upstream product

• 253185-03-4 tert-butylbenzene 
• 7065-46-5 3,3-dimethylbutanoic acid chloride 
• 1746-23-2 4-tert-Butylstyrene 
• 84379-72-6 1,3-dioxoisoindolin-2-yl 3,3-dimethylbutanoate 

Downstream Products

• 77387-77-0 1-(4-tert-Butylphenyl)-3,3-dimethyl-1-thioxo-2-butanon 
• 77387-79-2 1-(4-tert-Butylphenyl)-3,3-dimethyl-2-thioxo-1-butanon 
• 77387-71-4 2-Brom-1-(4-tert-butylphenyl)-3,3-dimethyl-1-butanon 

Relevant academic research and scientific papers

Switchable Decarboxylative Heck-Type Reaction and Oxo-alkylation of Styrenes with N-Hydroxyphthalimide Esters under Photocatalysis

The switchable visible-light-mediated decarboxylative Heck-type reaction and oxo-alkylation reaction of N-hydroxyphthalimide esters under photocatalysis were developed. Disubstituted or trisubstituted alkenes were obtained in good yield with high E-select

Preparation of Diaryl and Aryl tert-Butyl α-Thioxoketones

The preparation of the α-haloketones 6, 13-16, 19, and 20 is reported. 13 or its precursor, the acyloin 9, respectively, is conveniently obtained by a Seebach synthesis. - Reaction of the haloketones with tetraethylammonium thiosulfate (21) yields the Bunte salts 22-27 wich form the thioketones 28-33 on cleavage with aqueous alkali. 29 is stable as a crystalline, blue monomer in contrast with other aromatic α-thioxoketones.This ist also true for the aromatic-aliphatic derivatives 30 and 31 as well as their isomers 32 and 33 wich do not dimerize.