77399-35-0

Upstream product

• 77399-34-9 (E)-4-((5S,6R)-2,5,6-Trimethyl-cyclohex-1-enyl)-but-3-en-2-one 
• 77346-44-2 (+)-(5S,6R)-2,5,6-trimethyl-1-cyclohexene-1-carbaldehyde 

Downstream Products

• 77399-36-1 (S)-3-Methyl-5-[(5S,6R)-2,5,6-trimethyl-cyclohex-2-en-(E)-ylidene]-pent-1-yn-3-ol 
• 77399-37-2 (R)-3-Methyl-5-[(5S,6R)-2,5,6-trimethyl-cyclohex-2-en-(E)-ylidene]-pent-1-yn-3-ol 

Relevant academic research and scientific papers

Synthesis and Absolute Configuration of Naturally Occurring Dactyloxene-B and -C

Natural (+)-dactyloxene-B (12) and -C (13) have been synthesized starting from (+)-trans-2,5,6-trimethyl-1-cyclohexene-1-carbaldehyde (1) which is shown to have the (5S,6R)-configuration by chemical correlation with (+)-(2R,3S,6S)-2,3,6-trimethylcyclohexa