77412-99-8Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling reactions of triorganoindium compounds with vinyl and aryl triflates or iodides
Perez, Ignacio,Sestelo, Jose Perez,Sarandeses, Luis A.
, p. 1267 - 1269 (1999)
(matrix presented) A novel palladium-catalyzed cross-coupling reaction of organoindium compounds with vinyl and aryl triflates or iodides is described. The reaction proceeds for alkyl-, vinyl-, alkynyl-, and arylindium compounds in excellent yields and high chemoselectivity without any excess of the organometallic. Remarkably, indium organometallics transfer efficiently the three organic groups attached to the metal.
Atom-efficient metal-catalyzed cross-coupling reaction of indium organometallics with organic electrophiles
Perez,Sestelo,Sarandeses
, p. 4155 - 4160 (2007/10/03)
The novel metal-catalyzed cross-coupling reaction of indium organometallics with organic electrophiles is described. Triorganoindium compounds (R3In) containing alkyl, vinyl, aryl, and alkynyl groups are efficiently prepared from the correspond
A NEW METHOD OF OLEFIN SYNTHESIS. COUPLING OF LITHIUM DIALKYLCUPRATES WITH ENOL TRIFLATES
McMurry, John E.,Scott, William J.
, p. 4313 - 4316 (2007/10/02)
Enol trifluoromethanesulfonates react with lithium dialkylcuprates to give the coupling products in high yields.The reaction is stereoselective and is successful with a wide variety of organocuprates , including methyl, butyl, phenyl, vinyl, and cycloprop
