77414-36-9Relevant academic research and scientific papers
Reversal of the Ritter Reaction as Observed Under Electron Impact Conditions
Nagubandi, Sreeramulu
, p. 535 - 538 (1980)
Fragmentations of various 2-phenethylamides, trifluoroacylimidates and imidoyl triflouromethyl sulfonates have been studied and a pathway for the formation of retro-Ritter reaction products is proposed.
The mechanism of the Bischler-Napieralski Reaction
Nagubandi, Sreeramulu,Fodor, G.
, p. 1457 - 1463 (2007/10/02)
The Bischler-Napieralski dihydroisoquinoline synthesis was proven to occur via imidoyl chlorides and the corresponding nitrilium salt.Two-step process required much milder conditions (20 degC - 50 degC) compared to drastic classical conditions of refluxing at 100 degC - 200 degC.The Bischler-Napieralski reaction is shown to share a common intermediate with two other well-known reactions: the von Braun and the Ritter reactions
