77419-45-5Relevant academic research and scientific papers
Development of oxidative formylation and ketonylation reactions
Ambrosini, Lisa M.,Cemak, Tim A.,Lambert, Tristan H.
experimental part, p. 870 - 881 (2010/10/02)
The first oxidative formylation and oxidative ketonylation of alkenylamines and alkenyl alcohols is demonstrated. A range of substrates that participate in this process are provided. Oxidative formylation was found to proceed optimally with the use of triphenylsilane as the hydride source. Oxidative ketonylation was feasible with a number of organometallic partners, especially dialkylzinc or organostannanes. An interesting finding regarding the fate of various acylpalladium intermediates is discussed. Georg Thieme Verlag Stuttgart.
