77437-59-3

Upstream product

• 25320-59-6 tetra-O-benzyl glucopyranosyl chloride 
• 77437-58-2 2,3,4-Tri-O-acetyl-6-O-(2,3,4-tri-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranosyl azide 
• 77437-57-1 Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-((2R,3R,4S,5R,6S)-3,4,5-triacetoxy-6-azido-tetrahydro-pyran-2-ylmethoxy)-2-trityloxymethyl-tetrahydro-pyran-3-yl ester 

Downstream Products

• 77437-61-7 O-(2,3,4-Tetra-O-benzyl-α-D-glucopyranosyl)-(1->6)-O-(β-D-glucopyranosyl)-(1->6)-α-D-glucopyranoside azide 

Relevant academic research and scientific papers

Synthetic Studies on Nephritogenic Glycosides. Synthesis of α-Glc-(1->6)-β-Glc-(1->6)-α-Glc-(1->Asn)

Glucotriosyl asparagine 2, a proposed structure for the glycan part of nephritogenic glucopeptide 1 isolated from the glomerular basement-membrane of rat, was synthesized in regio- and stereo-selective manners starting from α-D-glycopyranosyl azide 8.The key intermediate for this synthesis was designed to be glucotriosyl azide 21, based on retrosynthetic considerations.