774581-23-6

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 2-(2-cyanoethyl)-, methyl ester
• Synonyms: 1-Pyrrolidinecarboxylic acid, 2-(2-cyanoethyl)-, methyl ester
• CAS NO: 774581-23-6
• Molecular Formula: C9H14N2O2
• Molecular Weight: 0
• Mol File: 774581-23-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 2-(2-cyanoethyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 2-(2-cyanoethyl)-, methyl ester(774581-23-6)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 2-(2-cyanoethyl)-, methyl ester(774581-23-6)

Safety Data

• Hazardous Substances Data: 774581-23-6(Hazardous Substances Data)

Upstream product

• 56475-80-0 N-(methoxycarbonyl)pyrrolidine 
• 107-13-1 acrylonitrile 

Relevant articles and documents

Generation of carbon free radicals by reduction of the cation pool

The electrochemical reduction of N-acyliminium ions, which were generated by the "cation pool" method, led to the formation of carbon free radicals. Carbon radicals thus generated underwent homo-coupling reactions and the reactions with activated olefins, such as methyl acrylate. In the latter case, a mechanism involving the addition of a carbon radical to the carbon-carbon double bond, followed by one-electron reduction to give carbanions, has been proposed. The present study opens a new possibility for radical-mediated carbon-carbon bond formation based on the reduction of carbocations.