77469-10-4Relevant academic research and scientific papers
vic-Iodothiocyanates and Iodoisothiocyanates. Part 8. Addition of Iodine-Thiocyanogen to Alkenes under Ionic and Radical Conditions
Cambie, Richard C.,Rutledge, Peter S.,Strange, Gary A.,Woodgate, Paul D.
, p. 553 - 565 (2007/10/02)
Addition of iodine-thiocyanogen to alkenes in the dark proceeds by a regioselective ionic reaction to give mainly vic-iodoisothiocyanates, and under irradiation with u.v. light by a radical reaction to give mainly vic-iodothiocyanates.However, in the case of 1-methylene-4-t-butylcyclohexane even under irradiation by u.v. light, ionic addition of the reagent competes successfully with, and almost to the exclusion of, the radical pathway.
vic-Iodothiocyanates and Iodoisothiocyanates. Part 3. Further Preperations, and the Formation of 2-Alkoxy-2-thiazolines
Cambie, Richard C.,Chambers, David,Rutledge, Peter S.,Woodgate, Paul D.,Woodgate, Shella D.
, p. 33 - 39 (2007/10/02)
The reactions of (E)-hex-3-ene, 4-t-butylcyclohexene, and 3-t-butylcyclohexene with iodine and potassium thiocyanate are examined.The action of iodine and thiocyanogen with (E)-hex-3-ene gives different results from those reported in the literature.Isomerization of the vic-iodothiocyatates and formation of 2-alkoxy-2-thiazolines from the latter adducts are reported.
