77492-65-0

Basic information

• Product Name: 7-(1-adamantyl)-7,8-dihydro-2-methylquinoline
• Synonyms: 7-(1-adamantyl)-7,8-dihydro-2-methylquinoline
• CAS NO: 77492-65-0
• Molecular Weight: 279.425
• Mol File: 77492-65-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-(1-adamantyl)-7,8-dihydro-2-methylquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(1-adamantyl)-7,8-dihydro-2-methylquinoline(77492-65-0)
• EPA Substance Registry System: 7-(1-adamantyl)-7,8-dihydro-2-methylquinoline(77492-65-0)

Safety Data

• Hazardous Substances Data: 77492-65-0(Hazardous Substances Data)

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 92-46-6 6-chloro-2-methylquinoline 

Relevant articles and documents

Electrolytic Adamantylation by Reductive Coupling of Quinolinylhalides in the Presence of 1-Bromoadamantane

Electrochemically generated anion radicals of a number of halogen-substituted quinolines 1a-g dehalogenate in N,N-dimethylformamide to halogen anions and radicals, which may stabilize by hydrogen abstraction from the solvent.In the presence of 1-bromoadamantane the fragments of reductive dehalogenation may be used synthetically for indirect generation of 1-bromoadamantane-radicals, which react predominantly to cross-coupled 2- and 7-monoadamantylated dihydroquinoline- and quinoline-structures, independent of the original halogen position.If C-2 is blocked, adamantylation takes place in the carbocyclic ring.Product distribution and cyclic-voltammetric results are discussed in terms of mechanism.