77495-28-4

Upstream product

• 17920-90-0 3,3,7-trimethyl-oct-6-enal 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 

Downstream Products

• 77495-30-8 trans-2-Isopropyl-5,5-dimethylcyclohexylamine 
• 77495-29-5 ((1R,2S)-2-Isopropenyl-5,5-dimethyl-cyclohexyl)-((R)-1-phenyl-ethyl)-amine 

Relevant academic research and scientific papers

Biomimetic Polyene Cyclizations. Asymmetric Induction during the Acid-Catalyzed Cyclization of Chiral Imines

This paper reports the details of a basic study showing that an imino function is suitable to initiate acid-catalyzed cyclizations of polyenes, affording high yields of cyclized products.The additional advantage of such a function is to introduce very easily a chirality on the polyene skeleton by the way of a chiral group linked to nitrogen.The extent of asymmetric induction by a chiral phenethyl group on nitrogen is from 36percent to 65percent, according to the monocyclic or bicyclic nature of the substrate.