77499-98-0Relevant academic research and scientific papers
HYDROLYSIS KINETICS AND MECHANISM OF DIARYLTHIOCARBAMATES IN 20percent AQUEOUS DIOXANE MEDIUM
Mindl, Jaromir,Balcarek, Pavel,Silar, Lubomir,Vecera, Miroslav
, p. 3130 - 3139 (2007/10/02)
Substituted S-aryl and O-aryl N-arylthiocarbamates have been synthetized.Kinetic studies of hydrolysis of these compounds in 20percent aqueous dioxane prove the ElcB mechanism.The found Hammett reaction constants, activation entropy values, Broensted coefficients, and comparison of reactivity with N-methyl analogues have been discussed as criteria of the mentioned mechanism.Hydrolysis results of thiocarbamates and carbamates in the same medium are compared.
