775-54-2Relevant articles and documents
An unexpected (3 → 2)-hydride shift in phyllocladane (=13β-kaurane) diterpenoids and in related trimethyl-substituted Bi- and tricyclic compounds
Mueller, Ralph,Rueedi, Peter
, p. 439 - 456 (2007/10/03)
The conversion of 2α,3α-dioxy-substituted phyllocladane derivatives into the corresponding 3-ketone proceeds in an unexpected manner: Depending on the reaction conditions, the corresponding 3β-hydroxy-substituted compound is formed almost quantitatively,