7750-00-7Relevant academic research and scientific papers
Preparative scale application of Mucor circinelloides ene–reductase and alcohol dehydrogenase activity for the asymmetric bioreduction of α,β-unsaturated γ-ketophosphonates
Janicki, Ignacy,Kie?basiński, Piotr,Szel?g, Jakub,G??bski, Adrian,Szcz?sna-Antczak, Miros?awa
supporting information, (2020/01/28)
The fungus Mucor circinelloides exhibits high potential for green chemistry and technological applications. Recently M. circinelloides, which so far was considered mainly as a platform for biodiesel production, was found to exhibit high ene-reductase acti
Reaction of Dialkyl Phosphites with α-Enones, II. - 2:1 Adducts from Dimethyl Phosphite and α-Enones: Synthesis of (1-Hydroxy-1,3-alkanediyl)diphosphonates and 5-Dimethoxyphosphoryl-2-methoxy-1,2-oxaphospholane P-Oxides
Oehler, Elisabeth,Zbiral, Erich
, p. 229 - 236 (2007/10/02)
On NaOCH3-catalyzed reaction with two equivalents of dimethyl phosphite (2), various α-enones 1 are transformed into the diphosphonates 5 (e.g. 5a, 5b, 5e, 5f), which, depending on the structure of the enone, can further react with ring closure to give th
Reaction of benzalacetone with dimethylphosphorous acid
Arbuzov,Zoroastrova,Tudrii,Fuzhenkova
, p. 2541 - 2542 (2007/10/13)
1. In the presence of an equimolar amount of diethylamine or a catalytic amount of sodium methylate, dimethylphosphorous acid adds to the carbonyl group of benzalacetone to give the dimethyl ester of 4-phenyl-2-hydroxy-3-butenyl-2-phosphonic acid. 2. An equimolar amount of sodium methylate favors the formation of the dimethyl ester of 1-phenyl-2-acetylethylphosphonic acid.
