77507-17-6

Basic information

• Product Name: N-(1-Cyclohexylethyl)-α-<1-(9-anthryl)-2,2,2-trifluoroethoxy>acetamide
• Synonyms: N-(1-Cyclohexylethyl)-α-<1-(9-anthryl)-2,2,2-trifluoroethoxy>acetamide
• CAS NO: 77507-17-6
• Molecular Weight: 443.509
• Mol File: 77507-17-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(1-Cyclohexylethyl)-α-<1-(9-anthryl)-2,2,2-trifluoroethoxy>acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-Cyclohexylethyl)-α-<1-(9-anthryl)-2,2,2-trifluoroethoxy>acetamide(77507-17-6)
• EPA Substance Registry System: N-(1-Cyclohexylethyl)-α-<1-(9-anthryl)-2,2,2-trifluoroethoxy>acetamide(77507-17-6)

Safety Data

• Hazardous Substances Data: 77507-17-6(Hazardous Substances Data)

Upstream product

• 53531-34-3 (R)-2,2,2-trifluoro-1-(9-anthryl)ethanol 
• 4352-49-2 1-cyclohexylethylamine 
• 161905-71-1 (R)-α-<1-(9-Anthryl)-2,2,2-trifluoroethoxy>acetic acid 

Relevant articles and documents

Nuclear Magnetic Resonance Determination of Enantiomeric Composition and Absolute Configuration of Amines, Alcohols, and Thiols with α-acetic Acid as a Chiral Derivatizing Agent.

(R)-acetic acid, easily prepared from commercially available (R)-2,2,2-trifluoro-1-(9-anthryl)ethanol, is a useful chiral reagent for the conversion of enantiomeric alcohols, thiols, or amines into diastereomeric derivatives.The resultant diasteremers typically have nonidentical NMR spectra, thus enabling NMR determination of the diastereomeric ratio, a ratio which reflects the original enantiomeric purity of the alcohol, thiol, or amine.A discussion of the conformational behavior of these derivatives is presented as is a conformational model for obtaining absolute configurations of the alcohol, thiol, or amine from the senses of the chemical shift differences noted between the diastereomeric derivatives.