77515-22-1

Upstream product

• 127-08-2 potassium acetate 
• 77515-16-3 4aβ-chloro-octahydro-5α-phenylthio-8aβ-methylnaphthalen-1(2H)-one 
• 77515-14-1 octahydro-4aβ-hydroxy-5α-phenylthio-8aβ-methylnaphthalen-1(2H)-one 
• 108-98-5 thiophenol 
• 41867-59-8 (R)-8a-Methyl-3,4,6,7,8,8a-hexahydro-2H-naphthalen-1-one 
• 77515-13-0 4aβ,5β-epoxyoctahydro-8aβ-methylnaphthalen-1(2H)-one 
• 77515-13-0 4aα,5α-epoxyoctahydro-8aβ-methylnaphthalen-1(2H)-one 
• 77515-14-1 octahydro-4aα-hydroxy-5β-phenylthio-8aβ-methylnaphthalen-1(2H)-one 
• 77515-16-3 4aα-chloro-octahydro-5β-phenylthio-8aβ-methylnaphthalen-1(2H)-one 

Downstream Products

• 77515-35-6 (5S,8aR)-5-Benzenesulfinyl-8a-methyl-3,5,6,7,8,8a-hexahydro-2H-naphthalen-1-one 
• 77515-35-6 (5R,8aR)-5-Benzenesulfinyl-8a-methyl-3,5,6,7,8,8a-hexahydro-2H-naphthalen-1-one 

Relevant academic research and scientific papers

Synthetic Studies of Withanolides. Part 2. Synthesis of 4aβ,5β-Epoxy-4a,5,6,7,8,8a-hexahydro-4β-hydroxy-8aβ-methylnaphthalen-1(4H)-one and Related Compounds

The title compounds, a simple AB ring moiety of withaferin A, and its seven isomers, were synthesized via octahydro-4a-hydroxy-5-(phenylthio)-8a-methylnaphthalen-1(2H)-ones .The key steps in the synthesis involve either 1,2-phenylthio-migra