77517-58-9

Upstream product

• 77517-57-8 (S)-2-[(3S,9S,10R,13R,14R,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl]-propan-1-ol 
• 82268-13-1 3β-tetrahydropyranyloxy-23,24-dinorchola-5,7-dien-22-ol p-toluenesulfonate 
• 114585-94-3 5α,8α-(1,4-Dioxo-1,2,3,4-tetrahydrophthalazin-2,3-ylen)-3β-(tetrahydropyran-2-yloxy)-23,24-bisnorchol-6-en-22-ol 
• 873-55-2 sodium benzenesulfonate 
• 82268-14-2 22-bromo-3β-tetrahydropyranyloxy-23,24-dinorchola-5,7-diene 
• 116653-43-1 5α,8α-(1,4-dioxo-1,2,3,4-tetrahydrophthalazin-2,3-ylene)-3β-(2H-tetrahydropyran-2-yloxy)-23,24-bisnorchol-6-en-22-yl-4-toluenesulfonate 
• 121262-49-5 5α,8α-(1,4-dioxo-1,2,3,4-tetrahydrophthalazin-2,3-ylene)-3β-(2H-tetrahydropyran-2-yloxy)-23,24-bisnorchol-6-en-22-yl benzenesulfonate 
• 121262-50-8 5α,8α-(1,4-dioxo-1,2,3,4-tetrahydrophthalazin-2,3-ylene)-3β-(2H-tetrahydropyran-2-yloxy)-23,24-bisnorchol-6-en-22-yl methanesulfonate 
• 121262-47-3 C₃₅H₄₅BrN₂O₄ 

Downstream Products

• 55721-11-4 24(R),25-dihydroxycholecalciferol 
• 77517-60-3 (24R)-22ξ-phenylsulfonyl-3β-(2H-tetrahydropyran-2-yloxy)cholesta-5,7-diene-24,25-diol 
• 79199-85-2 (S)-5-Benzenesulfonyl-6-[(3S,9S,10R,13R,14R,17R)-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl]-2-methyl-heptane-2,3-diol 

Relevant academic research and scientific papers

An Improved Synthesis of (24R)-3β-(2H-Tetrahydropyran-2-yloxy)cholesta-5,7-diene-24,25-diol - a Key Intermediate in the Synthesis of (24R)-24,25-Dihydroxyvitamin D3

A multistep procedure for the conversion of ergosterol into the tetrahydropyranyl ether of (24R)-24,25-dihydroxyprovitamin D3 using 1,4-dihydrophthalazine -1,4-dione as diene protecting agent was compared with an established route, which uses 4